Pyridinium Dichromate (PDC)

Pyridinium Dichromate (PDC), also known as the Cornforth Reagent, is a selective oxidizing agent used in organic synthesis. It is closely related to PCC but offers improved solubility in a wider range of organic solvents.


CAS Number 20039-37-6
Chemical Formula C10H12Cr2N2O7
Molecular Weight 376.20 g/mol
Appearance Bright orange to orange-red crystalline powder
Melting Point 144 – 150 °C (decomposes on melting)
Purity ≥ 98.0%
Solubility Highly soluble in DMF and DMSO;
moderately soluble in Dichloromethane (DCM) and Acetonitrile
Safety Information Contains Hexavalent Chromium (Cr6+) and must be handled
with extreme care. Appropriate safety measures are required.
Packing Laboratory packs: 100 g, 500 g, 1 Kg amber glass bottles
Industrial packs: 25 Kg fiber drums with double-layered
antistatic PE liners
Synonyms PDC,
Cornforth Reagent,
Pyridinium binoxotrioxochromate (VI),
Dichromic acid, bis(pyridinium) salt
Uses A mild and nearly neutral oxidant used to convert primary and
secondary alcohols into aldehydes or ketones. When dissolved in
DMF, it can further oxidize non-conjugated primary alcohols
into carboxylic acids.

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